Bulk Hyperpolarization of Inorganic Materials

Porous Inorganic Materials

M41S: A family of mesoporous materials including MCM41, MCM-48, and MCM-50 MSU-1,2,3,4: Michigan State University no. 1, 2, 3, 4, a series of wormhole mesoporous materials prepared in the presence of nonionic surfactants Pluronic: polyethylene oxide–polypropylene oxide triblock surfactant, (EO)m(PO)n(EO)m, for example, P123 = (EO)20 (PO)70(EO)20 SBA-x: Santa Barbara no. x, a series of mesoporou...

Bulk Behavior of Nanostructured Materials

Thermal Rectification Using Bulk Materials

In conduction, thermal rectification occurs when a material or structure transfers heat asymmetrically. In this work, it is shown that, in the bulk, the necessary condition for thermal rectification is that the thermal conductivity of the material or structure be a function of both space and temperature, and that this function is not separable. Practically, this can be achieved using a composit...

Molecular design of hybrid organic-inorganic materials

Hybrid organic-inorganic materials offer a wide range of interesting applications especially in optics. Chemistry plays a major role in the elaboration and comprehension of such materials. Sol-gel process provide a method to blend, down to the molecular scale, organic and inorganic components. Examples of hybrid organic-inorganic materials for optics and optical characterizations of hybrid mate...

Synthesis of inorganic heptazine-based materials

This dissertation describes research on the synthesis and characterization of extended heptazine-based, graphite-like carbon nitride materials (CNx), as well as molecular heptazine (C6N7) derivatives. Spurred on by recent triazine to heptazine conversion studies, a structural examination was performed on an amorphous nitrogenrich carbon nitride material formed via the rapid and exothermic self-...